Title of article
A cationic 24-MC-8 manganese cluster with ring metals possessing three oxidation states [MnII4MnIII6MnIV2 ((mu)4-O)2((mu)3-O)4((mu)3-OH)4((mu)3-OCH3)2(pko)12](OH)(ClO4)3
Author/Authors
Pecoraro، Vincent L. نويسنده , , Kampf، Jeff W. نويسنده , , Dendrinou-Samara، Catherine نويسنده , , Zaleski، Curtis M. نويسنده , , Evagorou، Andri نويسنده , , Kessissoglou، Dimitris P. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-2667
From page
2668
To page
0
Abstract
Reaction of Mn(ClO4)2 with di-pyridyl ketone oxime, (2-py)2CNOH, gives the novel cluster [MnII4MnIII6MnIV2((mu)4-O)2((mu)3-O)4((mu)3-OH)4((mu)3-OCH3)2(pko)12](OH)(ClO4)3 1. It is the only example of a 24 -MC-8, and the first metallacrown with ring metal ions in three different oxidation states. Magnetic measurements show antiferromagnetic behavior.
Keywords
evolution galaxies , starburstinfrared
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
68809
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