Title of article
A new class of organic donor–acceptor molecules with large third-order optical nonlinearities
Author/Authors
Gisselbrecht، Jean-Paul نويسنده , , Gross، Maurice نويسنده , , Michinobu، Tsuyoshi نويسنده , , May، Joshua C. نويسنده , , Lim، Jin H. نويسنده , , Boudon، Corinne نويسنده , , Seiler، Paul نويسنده , , Biaggio، Ivan نويسنده , , Diederich، Francois نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-736
From page
737
To page
0
Abstract
Donor–acceptor molecules with 4-(dimethylamino)phenyl donor and 1,1,4,4-tetracyanobuta-1,3-diene acceptor moieties are readily prepared by short, high-yielding routes. The quite small chromophores are characterised by X-ray crystallography and feature intense intramolecular charge-transfer bands, substantial quinoid character in the donor rings, reversible electrochemical reductions and oxidations and powerful third-order optical nonlinearities.
Keywords
molecular processes , ISM: molecules , molecular data
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
68909
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