Title of article :
Stabilisation of eudesmane cation by tryptophan 334 during aristolochene synthase catalysis
Author/Authors :
Deligeorgopoulou، Athina نويسنده , , Taylor، Susan E. نويسنده , , Forcat، Silvia نويسنده , , Allemann، Rudolf K. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
Analysis of the hydrocarbons produced during catalysis by mutants of aristolochene synthase from Penicillium roqueforti indicated that Trp 334 had a pivotal function for the efficient production of aristolochene from farnesylpyrophosphate most likely by stabilising the intermediate, eudesmane cation.
Keywords :
Identifiability , Restricted latent class models , Goodness of fit , Parametric bootstrap , Model diagnosis
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH