• Title of article

    Generation and aromaticity of 2-silaimidazolium ion, a new (pi)-conjugated silylium ion

  • Author/Authors

    West، Robert نويسنده , , Komatsu، Koichi نويسنده , , Ishida، Shintaro نويسنده , , Nishinaga، Tohru نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2005
  • Pages
    -777
  • From page
    778
  • To page
    0
  • Abstract
    A novel cationic silaaromatic, 2-silaimidazolium cation (5), was synthesized by chloride abstraction from the corresponding chlorosilane (4) with [Et3Si(benzene)]+· TPFPB–(TPFPB–= tetrakis(pentafluorophenyl)borate); cation 5 exists as a free silylium cation in solution due to bulky substituents on the five-membered ring.
  • Keywords
    molecular data , molecular processes , ISM: molecules
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2005
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    68972