Title of article
Generation and aromaticity of 2-silaimidazolium ion, a new (pi)-conjugated silylium ion
Author/Authors
West، Robert نويسنده , , Komatsu، Koichi نويسنده , , Ishida، Shintaro نويسنده , , Nishinaga، Tohru نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-777
From page
778
To page
0
Abstract
A novel cationic silaaromatic, 2-silaimidazolium cation (5), was synthesized by chloride abstraction from the corresponding chlorosilane (4) with [Et3Si(benzene)]+· TPFPB–(TPFPB–= tetrakis(pentafluorophenyl)borate); cation 5 exists as a free silylium cation in solution due to bulky substituents on the five-membered ring.
Keywords
molecular data , molecular processes , ISM: molecules
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
68972
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