Title of article :
Diastereoselective metal-catalyzed [4 + 2 + 2] carbocyclization reactions utilizing a rhodium N-heterocyclic carbene (NHC) complex: the first example of a rhodium NHC-catalyzed [m+n+o] carbocyclization
Author/Authors :
Pink، Maren نويسنده , , Evans، P. Andrew نويسنده , , Baum، Erich W. نويسنده , , Fazal، Aleem N. نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
The air and moisture stable rhodium N-heterocyclic carbene (NHC) complex, RhCl(IMes)(COD)(IMes =N,Nʹ-bis(2,4,6-trimethylphenyl)imidazole-2-ylidine; COD = 1,5-cyclooctadiene), facilitates a diastereoselective metal-catalyzed [4 + 2 + 2] carbocyclization of 1,6-enynes in the presence of silver triflate and 1,3-butadiene.
Keywords :
Euphorbia esula , Leafy spurge flea beetles , IPM , Endangered species , Spurgia esulae , Aphthona czwalinae , Invasive weeds , Aphthona nigriscutis , Aphthona lacertosa , Aphthona flava , Biological control
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
