• Title of article

    A quasi-covalent metal–metal bond in an early–late heterobimetallic Ti–Pt complex stabilized by phosphinoenolate ligands

  • Author/Authors

    Braunstein، Pierre نويسنده , , Morise، Xavier نويسنده , , Welter، Richard نويسنده , , Rohmer، Marie-Madeleine نويسنده , , Benard، Marc نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    -60
  • From page
    61
  • To page
    0
  • Abstract
    An unusual early–late bimetallic complex with direct metal–metal bonding is obtained from a phosphinoenolate ligand-assisted reaction between Ti(IV) and Pt(0) reagents which occurs by formal insertion of the Pt(0) centre into a Ti(IV)–O bond; X-ray data and EHMO calculations indicate the presence of a quasi-covalent Ti(III)–Pt(I) bond (2.721(2) ?).
  • Keywords
    Mellin transform , Brownian motion , Riemann zeta function , gamma process , Bessel process , characterization of distributions , Meixner process , Levy process
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2003
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    69150

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=69150