Title of article
Preparation of cyclic alkenylmagnesium reagents via an iodine/magnesium exchange
Author/Authors
Ren، Hongjun نويسنده , , Krasovskiy، Arkady نويسنده , , Knochel، Paul نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-542
From page
543
To page
0
Abstract
The reaction of various cyclic alkenyl iodides with i-PrMgCl·LiCl produces the corresponding alkenylmagnesium reagents under mild conditions. After reaction with various electrophiles, like allylic halides, disulfides, aldehydes and acid chlorides, the expected products are obtained in 53–91% yield. Remarkably, the mild conditions of the I/Mgexchange tolerate the presence of sensitive diene functionalities.
Keywords
Spurgia esulae , Biological control , Invasive weeds , Euphorbia esula , IPM , Endangered species , Aphthona czwalinae , Leafy spurge flea beetles , Aphthona flava , Aphthona nigriscutis , Aphthona lacertosa
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69360
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