Title of article :
Formation of a long-lived charge-separated state of a zinc phthalocyanine-perylenediimide dyad by complexation with magnesium ion
Author/Authors :
Gutiérrez، Ana M. نويسنده , , Ohkubo، Kei نويسنده , , Fukuzumi، Shunichi نويسنده , , Ortiz، Javier نويسنده , , Fernandez-Lazaro، Fernando نويسنده , , Sastre-Santos، angela نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
Photoexcitation of a zinc phthalocyanine–perylenediimide (ZnPc–PDI) dyad affords the triplet excited state without the fluorescence emission, whereas addition of Mg^2+ to the photoexcited ZnPc–PDI results in formation of a long-lived charge-separated state (ZnPc(bullet)^+ –PDI(bullet)–/Mg^2+) in which PDI(bullet)^– forms a complex with Mg^2+.
Keywords :
molecular processes , ISM: molecules , molecular data
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
