Title of article
The first example of enantioselective isocyanosilylation of meso epoxides with TMSCN catalyzed by novel chiral organogallium and indium complexes
Author/Authors
PAN، Yi نويسنده , , Zhu، Chengjian نويسنده , , Yuan، Fang نويسنده , , Gu، Weijin نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-691
From page
692
To page
0
Abstract
The desymmetrization ring opening of meso epoxides using trimethylsilyl cyanide catalyzed by organogallium and indium complexes with binaphthol monoether derivatives as chiral ligands gave (beta)-isocyanohydrins with moderate to excellent enantioselectivities of up to 95% ee.
Keywords
asynchronously automatic group , combing , second order Dehn function
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69601
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