Title of article
The role of the counteranion in the cation-(pi) interaction
Author/Authors
Hunter، Christopher A. نويسنده , , Low، Caroline M. R. نويسنده , , Rotger، Carmen نويسنده , , Vinter، Jeremy G. نويسنده , , Zonta، Cristiano نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-833
From page
834
To page
0
Abstract
Chemical double mutant cycles have been used to quantify cation-(pi) interactions in chloroform as a function of the nature of the counteranion. The cation-(pi) interaction is –2.5 ± 0.4 kJ mol–1 and independent of the anion, even though the overall stability of the complexes varies by an order of magnitude due to competition of the anion for alternative binding sites.
Keywords
second order Dehn function , asynchronously automatic group , combing
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69796
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