• Title of article

    Oxo-bridged metal carbene complexes. Synthesis, structure and reactivities of {[Os(Por)(CPh2)]2O}(Por = porphyrinato dianion)

  • Author/Authors

    Li، Yan نويسنده , , Che، Chi-Ming نويسنده , , Huang، Jie-Sheng نويسنده , , Zhou، Zhong-Yuan نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    -1361
  • From page
    1362
  • To page
    0
  • Abstract
    Dinuclear (mu)-oxo osmium porphyrins containing terminal Os=CPh2 bonds with a linear C=Os–O–Os=C moiety were prepared, which are reactive toward pyridine to form [Os(Por)(CPh2)(py)] and are active catalysts for inter- and intra-molecular cyclopropanation of alkenes and for carbene insertion into saturated C–H bonds.
  • Keywords
    Sulphur dioxide , atmospheric VOC , isoprene oxidation , inhibition of S(IV) autoxidation , isoprene
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2003
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    69845

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=69845