Title of article
Origin of 1,3-induction in the addition of alkyl lithium to imines bearing an N-stereogenic center
Author/Authors
Weil, Nancy، نويسنده , , Venugopalan، P. نويسنده , , Bharatam، Prasad V. نويسنده , , Ghosh، Soma نويسنده , , Singh، Nishan نويسنده , , Nanda، Gurmeet Kaur نويسنده , , Trehan، Sanjay نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-141
From page
142
To page
0
Abstract
The origin of diastereoselectivity in the addition of alkyl lithium to chiral Schiff bases has been investigated experimentally and theoretically and the formation of the major diastereomer can be explained from the energy minimized structure of the Schiff base in which the phenyl group has been found to orient in such a manner that it posed lesser steric hindrance to the incoming nucleophile as compared to the alkyl group
Keywords
isoprene oxidation , Sulphur dioxide , atmospheric VOC , isoprene , inhibition of S(IV) autoxidation
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
69966
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