Title of article
Preparation, X-ray structure and reactivity of a stable glycosyl iodide
Author/Authors
Bickley، Jamie F. نويسنده , , Hughes، David L. نويسنده , , Field، Robert A. نويسنده , , Harding، John R. نويسنده , , Cottrell، Jennifer A. نويسنده , , Ferguson، John R. نويسنده , , Kartha، K. P. Ravindanathan نويسنده , , Law، Jayne L. نويسنده , , Scheinmann، Feodor نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-1265
From page
1266
To page
0
Abstract
Highly selective reaction of methyl tetra-O-pivaloyl-(beta)-D-glucopyranuronate 2 with iodotrimethylsilane or (Me3Si)2 and I2 affords, in excellent yield, the ʹdisarmedʹ glycosyl iodide 1 which has good stability at 20 °C and excellent stability at 0 °C; the X-ray crystal structure of 1 is described, along with a comparison of its utility as a glycosyl donor to that of the corresponding bromide.
Keywords
second order Dehn function , asynchronously automatic group , combing
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70080
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