Title of article :
New insight into a convenient base-promoted synthesis of Ru3(CO)12
Author/Authors :
Faure، Matthieu نويسنده , , Saccavini، Catherine نويسنده , , Lavigne، Guy نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The addition of two equivalents of KOH per Ru under 1 atm CO at 75 °C to a mixture of [Ru(CO)2Cl2]n and [Ru(CO)3Cl2]2 generated in situ by carbonylation of 5 grams of RuCl3·3H2O in 2-ethoxyethanol, triggers a reaction cascade producing Ru3 (CO)12 in yields exceeding 90% within 45 minutes.
Keywords :
atmospheric VOC , inhibition of S(IV) autoxidation , Sulphur dioxide , isoprene , isoprene oxidation
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
