Title of article
High-yield one-step synthesis in water of [Pt3n(CO)6n]2– (n > 6) and [Pt38(CO)44]2–
Author/Authors
Zacchini، Stefano نويسنده , , Femoni، Cristina نويسنده , , Kaswalder، Francesco نويسنده , , Iapalucci، Maria Carmela نويسنده , , Longoni، Giuliano نويسنده , , Mehlstaubl، Marita نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-5768
From page
5769
To page
0
Abstract
Carbonylation of Na2PtCl6·6H2O, as well as K2PtCl6, in water under a CO pressure of 900 mm Hg selectively and quantitatively affords [Pt3n(CO)6n]^2- (n > 6) salts; conversely, their corresponding carbonylation at reduced CO pressure of 760–800 mm Hg leads to a convenient one-step synthesis of [Pt38(CO)44]^2-.
Keywords
molecular data , molecular processes , ISM: molecules
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70322
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