• Title of article

    Mechanism of ruthenium-catalyzed hydrogen transfer reactions. Evidence for a stepwise transfer of CH and NH hydrogens from an amine to a (cyclopentadienone)ruthenium complex

  • Author/Authors

    Backvall، Jan-E. نويسنده , , ell، Alida H. نويسنده , , Johnson، Jeffrey B. نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    -1651
  • From page
    1652
  • To page
    0
  • Abstract
    Kinetic deuterium isotope effects and racemization studies indicate that dehydrogenation of an amine by a (cyclopentadienone) ruthenium complex occurs via a slow (beta)-hydride elimination of coordinated amine followed by a proton transfer from nitrogen to carbonyl oxygen.
  • Keywords
    atmospheric VOC , inhibition of S(IV) autoxidation , Sulphur dioxide , isoprene , isoprene oxidation
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Serial Year
    2003
  • Journal title
    CHEMICAL COMMUNICATIONS - LETCHWORTH
  • Record number

    70397

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=70397