Title of article
An N-heterocyclic carbene as a bidentate hemilabile ligand: a synchrotron X-ray diffraction and density functional theory study
Author/Authors
Hanson، Jonathan C. نويسنده , , Dioumaev، Vladimir K. نويسنده , , Szalda، David J. نويسنده , , Franz، James A. نويسنده , , Bullock، R. Morris نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-166
From page
167
To page
0
Abstract
The N-heterocyclic carbene ligand IMes was shown by synchrotron crystallography and DFT computations to adopt a hemilabile bidentate coordination mode in CpM(CO)2(IMes)+B(C6F5)4–(M = Mo, W), with a C=C bond of one mesityl weakly coordinated to the metal.
Keywords
atmospheric VOC , isoprene , inhibition of S(IV) autoxidation , isoprene oxidation , Sulphur dioxide
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70433
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