Title of article
Asymmetric Carroll rearrangement of allyl (alpha)-acetamido-(beta)-ketocarboxylates catalysed by a chiral palladium complex
Author/Authors
Kuwano، Ryoichi نويسنده , , Murakami، Masahiro نويسنده , , Ishida، Naoki نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-3950
From page
3951
To page
0
Abstract
Asymmetric decarboxylative rearrangement (Carroll rearrangement) of allyl (alpha)-acetamido-(beta)-ketocarboxylates was catalysed by a palladium complex modified with a chiral phosphine ligand, giving optically active (gamma),(delta)-unsaturated (alpha)-aminoketones with up to 90% ee.
Keywords
PLAYBACK EXPERIMENTS , URGENCY-BASED , TONIC COMMUNICATION , VIGILANCE
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70443
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