Title of article
Noncatalytic mono-N-methylation of aniline in supercritical methanol: the kinetics and acid/base effect
Author/Authors
Sakai، Hideki نويسنده , , Abe، Masahiko نويسنده , , Takebayashi، Yoshihiro نويسنده , , Morita، Yoshinori نويسنده , , Yoda، Satoshi نويسنده , , Furuya، Takeshi نويسنده , , Sugeta، Tsutomu نويسنده , , Otake، Katsuto نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-3964
From page
3965
To page
0
Abstract
Aniline is easily N-methylated in supercritical methanol without catalyst at 350 °C and 0.237 g cm^–3 to give mono-N-methylaniline with high selectivity, and the reaction rate is increased by a small amount of base (LiOH, NaOH, KOH, and CH3ONa), indicating a difference in the reaction mechanism from the ordinary acid-catalyzed one.
Keywords
URGENCY-BASED , VIGILANCE , TONIC COMMUNICATION , PLAYBACK EXPERIMENTS
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70463
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