Title of article
Reactions of nitrogen oxides with heme models. Low temperature spectral characterization of the unstable nitratonitrosyl complex FeIII(TPP)(ONO2)(NO)
Author/Authors
Ford، Peter C. نويسنده , , Kurtikyan، Tigran S. نويسنده , , Martirosyan، Garik G. نويسنده , , Hakobyan، Manya E. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-1705
From page
1706
To page
0
Abstract
Reaction of NO gas with low temperature films of the (eta)2-nitrato model heme FeIII(TPP)(O2NO)(TPP =mesotetraphenylporphyrinato2–) leads to formation of the previously unknown (eta)1-nitrato nitrosyl species FeIII(TPP)(ONO2)(NO) as characterized by IR and optical spectroscopy with isotopically substituted nitrogen oxides.
Keywords
inhibition of S(IV) autoxidation , isoprene , atmospheric VOC , Sulphur dioxide , isoprene oxidation
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70505
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