Title of article
[{AuTl(C6Cl5)2(toluene)}2(dioxane)]: A striking structure that leads to a blue luminescence
Author/Authors
Laguna، Antonio نويسنده , , Olmos، M. Elena نويسنده , , Fernandez، Eduardo J. نويسنده , , Lopez-de-Luzuriaga، Jose Maria نويسنده , , Perez، Javier نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-175
From page
176
To page
0
Abstract
The complex [{AuTl(C6Cl5)2(toluene)}2(dioxane)] displays a structure with the thallium(I) center in an unprecedented trigonal planar environment, showing the shortest Au–Tl interaction ever found, a toluene molecule in a (eta)6-mode and the "disappearance" of the Tl(I) inert pair, usually stereochemically active. These characteristics are responsible for its unusual luminescent behaviour.
Keywords
atmospheric VOC , inhibition of S(IV) autoxidation , isoprene , Sulphur dioxide , isoprene oxidation
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2003
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70586
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