Title of article :
A two-dimensional clathrate hydrate sandwiched by planar arrays of a copper complex
Author/Authors :
Hirotsu، Masakazu نويسنده , , Kinoshita، Isamu نويسنده , , Nishioka، Takanori نويسنده , , Wright، L. James نويسنده , , Miyamoto، Riichi نويسنده , , Hamazawa، Rika Tanaka نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
The first structurally characterised example of a 2-D clathrate hydrate spontaneously assembles when [CuF(tptm)](1)(tptm = tris(2pyridylthio)methyl) crystallises from toluene/water solutions to produce a material in which planar arrays of [CuF(tptm)] sandwich and hydrogen bond to continuous 2-D sheets of water that incorporate toluene molecules at regular intervals.
Keywords :
Aminolysis of epoxides , Synthesis of (beta)-amino alcohols , Ti-MCM-41 , Titanosilicate molecular sieves
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH