Title of article :
Synthesis and catalytic activity of a chiral periodic mesoporous organosilica (ChiMO)
Author/Authors :
Corma، Avelino نويسنده , , Baleiz?o، Carlos نويسنده , , Gigante، Barbara نويسنده , , Das، Debasish نويسنده , , Alvaro، Mercedes نويسنده , , Garcia، Hermenegildo نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
A chiral vanadyl salen complex having two peripheral trimethoxysilyl groups has been used to obtain a chiral periodic mesoporous organosilica having MCM-41 periodicity and the two Si–CH2 groups anchored on the framework; this solid induces 30 % enantioselectivity in the cyanosilylation of benzaldehyde.
Keywords :
isoprene oxidation , Sulphur dioxide , inhibition of S(IV) autoxidation , isoprene , atmospheric VOC
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH