Author/Authors :
Uehara، Akira نويسنده , , Maeda، Yonezo نويسنده , , Furutachi، Hideki نويسنده , , Fujinami، Shuhei نويسنده , , Suzuki، Masatatsu نويسنده , , Murayama، Mizue نويسنده , , Shiohara، Amane نويسنده , , Yamazaki، Satoshi نويسنده , , Ogo، Seiji نويسنده , , Watanabe، Yoshihito نويسنده ,
Abstract :
Reaction of a diiron(III) complex having a xylta4– ligand (N,N,Nʹ,Nʹ-m-xylylenediamine tetraacetate) with H2O2 resulted in regioselective hydroxylation of the m-xylyl linker. The reaction mimics the self-hydroxylation of a phenylalanine side chain found for ribonucleotide reductase (R2-W48F/D84E).
Keywords :
inhibition of S(IV) autoxidation , isoprene oxidation , isoprene , Sulphur dioxide , atmospheric VOC
