Title of article :
Dithiocarbamyl-substituted diphosphanylmethanide complexes of manganese(I): a new type of ambivalent metalloligands
Author/Authors :
Garcia-Granda، Santiago نويسنده , , Riera، Victor نويسنده , , Ruiz، Javier نويسنده , , Quesada، Roberto نويسنده , , Diaz، M. Rosario نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The diphosphanylmethanide complex [Mn(CO)4{(PPh2)2C–H}] promotes S–S bond breaking in tetramethylthiuram disulfide affording [Mn(CO)4{(PPh2)2C–S–C(S)NMe2}](2), which proved to be a valuable host for binding cations through the methanide carbon atom and the thiocarbonyl group, allowing the controlled synthesis of heterometallic compounds.
Keywords :
atmospheric VOC , inhibition of S(IV) autoxidation , isoprene oxidation , isoprene , Sulphur dioxide
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
Journal title :
CHEMICAL COMMUNICATIONS - LETCHWORTH
