Title of article
Controlled generation of heterochiral or homochiral coordination polymer: helical conformational polymorphs and argentophilicityinduced spontaneous resolution
Author/Authors
Mak، Thomas C. W. نويسنده , , Du، Miao نويسنده , , Chen، Xu-Dong نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-4416
From page
4417
To page
0
Abstract
In the pair of helical conformational polymorphs of the coordination polymer {[AgL](CF3SO3)}(infinity)(L = 2-pyridinyl-3pyridinylmethanone), the 21 helices of opposite chirality in one supramolecular isomer are stacked alternately to form a racemate, while the 41 helices in the other are assembled homochirally by inter-chain argentophilic interaction to generate a conglomerate.
Keywords
Oxidation , Fenton-like , H2O2 , Carbon-Fe catalysts , Orange II
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70830
Link To Document