Title of article
Rhodium-catalyzed tandem cyclization–cycloaddition reactions of enynebenzaldehydes: construction of polycyclic ring systems
Author/Authors
Oh، Chang Ho نويسنده , , Gupta، Arun Kumar نويسنده , , Shin، Seunghoon نويسنده , , Rhim، Chul Yun نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-4428
From page
4429
To page
0
Abstract
o-(1,6-Enynyl)benzaldehydes underwent a novel mode of cycloaddition using Rh(I)-precatalyst, via[3 + 2] cycloaddition of presumed dipolar carbonyl ylide intermediate generated by Rh-catalyst and the utility of this mechanistically intriguing enyne cyclization can be found in a number of polycyclic natural product skeletons.
Keywords
H2O2 , Fenton-like , Oxidation , Carbon-Fe catalysts , Orange II
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Serial Year
2005
Journal title
CHEMICAL COMMUNICATIONS - LETCHWORTH
Record number
70834
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