Title of article
Ion Formation in MALDI: The Cluster Ionization Mechanism
Author/Authors
Karas، Michael نويسنده , , Krüger، Ralf نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-426
From page
427
To page
0
Abstract
A novel organoruthenium(III) amidinate, ((eta)5-C5Me5)RuCl((eta)-iPrN(eta)C(Me)NiPr) (2), has been prepared by oxidation of organoruthenium amidinate, ((eta)5-C5Me5)Ru((eta)-iPrN(eta)C(Me)NiPr) (1), by organic chlorides; both 1 and 2 are found to be good catalysts for atom-transfer cyclization of N-allyltrichloroacetamides which are useful for successful preparation of a pyrrolizidine alkaloid skeleton under mild conditions.
Keywords
MALDI Ablation , Cluster Formation , Ion Velocity , Analyte , Matrix Crystal , Cluster lonization , photoionization , Interionic-Proton Transfer , MALDI Regimes
Journal title
CHEMICAL REVIEW - COLUMBUS
Serial Year
2003
Journal title
CHEMICAL REVIEW - COLUMBUS
Record number
70992
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