Title of article
Synthesis and Characterization of the Au11 Cluster with Sterically Demanding Phosphine Ligands by Single Crystal X-ray Diffraction and XPS Spectroscopy
Author/Authors
Yamaguchi، Tadashi نويسنده , , Ito، Tasuku نويسنده , , Onaka، Satoru نويسنده , , Nunokawa، Keiko نويسنده , , Nakamoto، Masami نويسنده , , Watase، Seiji نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
-1600
From page
1601
To page
0
Abstract
A new Au11 cluster with (m-CF3C6H4)3P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au11X3(PR3)7 clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF3 substituents at a meta-position of each phenyl ring of PR3 ligands.
Journal title
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Serial Year
2003
Journal title
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Record number
71601
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