Impact of nitrogen fertilizers on the natural weathering-erosion processes and fluvial transport in the Garonne basin

Knowledge of the impact of N-fertilizers on the weathering-erosion processes of soils in intensively cultivated regions is of prime importance. Nitrification of NH4− fertilizers produces HNO3 in the basin of the Garonne river, enhancing soil degradation. Their influence on the weathering rates was determined by calculating the consumption rate of atmospheric/soil CO2 by soil weathering and erosion, and its contribution to the total dissolved riverine HCO3−. This contribution was found to be less than 50% which corresponds normally to a complete carbonate dissolution by carbonic acid, suggesting that part of the alkalinity in the river waters is due to carbonate dissolution by an acid other than carbonic acid, probably HNO3.