Microchemical characterisation of natural gold and artefact gold as a tool for provenancing prehistoric gold artefacts: A case study in Ireland

The importance of Au to ancient societies has encouraged many archaeologists to search for the sources exploited in antiquity. These projects generally involve detailed studies of artefacts and comparison of their chemical characteristics with those reported for natural Au. However, descriptions of natural Au are frequently inadequate for provenancing studies, and the compositional variability of the material is not widely recognised. The present study describes a new approach to gold provenancing using the technique of microchemical characterisation in which populations of gold grains are classified according to the alloy compositions and the assemblages of microinclusions of other minerals. This technique, originally developed to identify sources of alluvial gold during Au exploration, has proved applicable to provenancing studies in four main areas. Firstly, microchemical characterisation of artefacts grouped according to archaeological criteria can indicate the number of sources exploited in relation to time and artefact taxonomy. Secondly, knowledge of the total variation in chemical characteristics of natural Au from a particular region provides an excellent database for provenancing and reduces the need for exhaustive sampling. Thirdly, it is possible to predict how Au alloys were modified during fabrication as a consequence of assimilation of mineral inclusions. Finally, identification of inclusion phases in artefact Au can provide information on metallurgical practices.