Physical characterization of particulate emissions from diesel engines: a review

Properties of particles emitted from diesel engines and the consequences of these properties for sampling and measuring the particles are reviewed. The influence of aftertreatment devices such as particle traps and catalytic converters on particle properties is demonstrated. Based on the particle properties and results from health effect studies, requirements to metrics, and measurement systems, for example, for type approval testing, are discussed. This discussion is limited to physical properties. Special attention is given to the volatile fraction. We show that care has to be taken when designing the sampling and dilution system, because this step decisively influences what happens with the volatile material, which may remain in the gas phase, condense on solid particles, or form new particles by nucleation. If nucleation occurs, particles formed in the sampling lines may dominate the particle number concentration. A selection of systems for dilution, conditioning and measuring is shown. Systems to determine number, mass, and surface concentrations, size distributions, and carbon concentration are discussed. The discussion is focused on systems developed or adapted recently for the physical characterization of diesel particles.