Author/Authors :
Roberto Sommariva، نويسنده , , Michael Trainer، نويسنده , , Joost A. de Gouw، نويسنده , , James M. Roberts، نويسنده , , Carsten Warneke، نويسنده , , Elliot Atlas، نويسنده , , Frank Flocke، نويسنده , , Paul D. Goldan، نويسنده , , William C. Kuster، نويسنده , , Aaron L. Swanson، نويسنده , , Fred C. Fehsenfeld، نويسنده ,
Abstract :
Secondary organic chemistry inside a typical urban plume in the North-East of the United States has been studied using a highly detailed chemical model, based upon the Master Chemical Mechanism (MCM). The model results have been qualitatively compared to measurements taken during three flights of the NOAA WP-3D aircraft, which sampled a plume from the New York City area during the NEAQS 2004 campaign. The model has been used to study the formation processes and photochemical evolution of alkyl nitrates.
While long-chain (C5) alkyl nitrates are produced for 90% or more from the oxidation of a single parent alkane, short-chain (
Keywords :
Urban plume , Photochemistry , alkyl nitrates , MCM , NEAQS
Journal title :
Atmospheric Environment
Journal title :
Atmospheric Environment