Author/Authors :
Riccardo Castagna، نويسنده , , Jason P. Eiserich، نويسنده , , Madhu S. Budamagunta، نويسنده , , Pierluigi Stipa، نويسنده , , Carroll E. Cross، نويسنده , , Elisa Proietti، نويسنده , , John C. Voss، نويسنده , , Lucedio Greci، نويسنده ,
Abstract :
We studied the reaction between hypochlorite anion (−OCl) and hydrogen peroxide (H2O2) by using spin-trapping agents such as 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) and 5-diethoxy-phosphoryl-5-methyl-1-pyrroline-N-oxide (DEPMPO). The obtained data demonstrate that hydroxyl radical is produced in this reaction. Thus, −OCl and H2O2 could assume new relevance in environmental chemistry by representing a potential source of hydroxyl radicals and other oxidant species, such as HO–OCl and OCl radical.