Title of article
Selective oxidation of sulfides to sulfoxides catalyzed by ruthenium (III) meso-tetraphenylporphyrin chloride in the presence of molecular oxygen
Author/Authors
Xian-Tai Zhou، نويسنده , , Hong-Bing Ji، نويسنده , , Zhao Cheng، نويسنده , , Jian-Chang Xu، نويسنده , , Li-Xia Pei، نويسنده , , Le-Fu Wang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
4
From page
4650
To page
4653
Abstract
Highly efficient selective oxidation of sulfides to sulfoxides by molecular oxygen catalyzed by ruthenium (III) meso-tetraphenylporphyrin chloride (Ru(TPP)Cl) with isobutyraldehyde as oxygen acceptor has been reported. In large-scale experiment of thioanisole oxidation, the isolated yield of sulfoxide of 92% was obtained and the turnover number reached up to 92,000.
Keywords
Ruthenium porphyrin , sulfide , Sulfoxide , Dioxygen
Journal title
Bioorganic & Medicinal Chemistry Letters
Serial Year
2007
Journal title
Bioorganic & Medicinal Chemistry Letters
Record number
798479
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