Title of article
The First Oligomeric Samarium(II) Silylamide: Coordinative Saturation through Agostic Sm···SiH Interactions
Author/Authors
Anwander، Reiner نويسنده , , Scherer، Wolfgang نويسنده , , Nagl، Iris نويسنده , , Tafipolsky، Maxim نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-1404
From page
1405
To page
0
Abstract
We provide a precise definition and analysis of quantum causal histories (QCHs). A QCH consists of a discrete, locally finite, causal pre-spacetime with matrix algebras encoding the quantum structure at each event. The evolution of quantum states and observables is described by completely positive maps between the algebras at causally related events. We show that this local description of evolution is sufficient and that unitary evolution can be recovered wherever it should actually be expected. This formalism may describe a quantum cosmology without an assumption of global hyperbolicity; it is thus more general than the Wheeler–De Witt approach. The structure of a QCH is also closely related to quantum information theory and algebraic quantum field theory on a causal set.
Keywords
Trinuclear complex , Agostic interactions , Transsilylamination , samarium , Silylamide
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Serial Year
1999
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Record number
83452
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