Title of article
Cycloisomerization of Alkynols at Transition Metal Templates
Author/Authors
Weyershausen، Bernd نويسنده , , Dotz، Karl Heinz نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-1056
From page
1057
To page
0
Abstract
The metal-assisted cycloisomerization of (omega)-alkynols to oxacycloalkylidene complexes is reviewed. A variety of low-valent coordinatively unsaturated transition metal templates from group 6 to 10 mediate the cyclization of (omega)-butynols, -pentynols, and -hexynols to give the corresponding oxacycloalkylidene complexes. In some cases kinetic hydroxyalkylvinylidene complex intermediates can be isolated and characterized.
Keywords
Isomerizations , Transition metal templates , Vinylidene complexes , Alkynols , Oxacycloalkylidene complexes
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Serial Year
1999
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Record number
83614
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