Title of article
A Square-Planar Dinickel(II) Complex with a Noninnocent Dinucleating Oxamate Ligand: Evidence for a Ligand Radical Species
Author/Authors
Ottenwaelder، Xavier G. نويسنده , , Aukauloo، Ally نويسنده , , Ruiz، Rafael نويسنده , , Poussereau، Sandrine نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-1066
From page
1067
To page
0
Abstract
The metal-assisted cycloisomerization of (omega)-alkynols to oxacycloalkylidene complexes is reviewed. A variety of low-valent coordinatively unsaturated transition metal templates from group 6 to 10 mediate the cyclization of (omega)-butynols, -pentynols, and -hexynols to give the corresponding oxacycloalkylidene complexes. In some cases kinetic hydroxyalkylvinylidene complex intermediates can be isolated and characterized.
Keywords
nickel , Polynuclear complexes , Radicals , Amides , Redox chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Serial Year
1999
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Record number
83615
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