Title of article
Group-4 Metallocene Cation Complexes of Oligopeptides: Reaction of [Cp2ZrCH3(THF)+BPh4-] with Boc-Protected Di- and Tripeptide Esters
Author/Authors
Erker، Gerhard نويسنده , , Bergander، Klaus نويسنده , , Frohlich، Roland نويسنده , , Wonnemann، Jorg نويسنده , , Oberhoff، Markus نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-1110
From page
1111
To page
0
Abstract
Various gold(I) complexes of aliphatic amines have been prepared by the reaction of chloro(tetrahydrothiophene)gold(I) with the respective amines. The stability of these complexes can be attributed partly to the formation of hydrogen bonds involving the N-H functions, and partly to aurophilic interactions. Analysis of these secondary contacts suggests an inverse correlation between lengths of aurophilic interactions and hydrogen bonds.
Keywords
Bioorganometallic chemistry , Zirconocene complexes , Metallocene cations , Group-4 metallocene peptide complexes
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Serial Year
1999
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Record number
83622
Link To Document