• Title of article

    Roles of (pi)-Alkyne, Hydride-Alkynyl, and Vinylidene Metal Species in the Conversion of Alkynes into Vinylidene: New Theoretical Insights

  • Author/Authors

    Mealli، Carlo نويسنده , , Ienco، Andrea نويسنده , , Paoli، Paola نويسنده , , Perez-Carreno، Enrique نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 1999
  • Pages
    -1314
  • From page
    1315
  • To page
    0
  • Abstract
    The new compounds K4Nb2S10O and Rb4Nb2S10O have been synthesized by the reaction of potassium or rubidium alkaline polychalcogenides with NbO2, Nb2O5, or mixtures of Nb and NbO. Their structures consist of discrete [Nb2Q11]4- anions (Q = O, S) built up of two face-sharing pentagonal bipyramids, which are connected via the alkali metal cations.
  • Keywords
    Ab initio calculations , EHMO , Vinylidene complexes , Cobalt , Rhodium
  • Journal title
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
  • Serial Year
    1999
  • Journal title
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
  • Record number

    83649

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=83649