Abstract :
The elimination of aromatic compounds present in surface water by photo-Fenton with sunlight as the source of
radiation was studied. The concentrations of Fe3+ and H2O2 are key factors for this process. A solar simulator and
a prototype parabolic collector were used as laboratory-scale reactors to find the parameters of those key factors to
be used in the CPC (compound parabolic collector) pilot plant reactor. The initial mineralization rate constant (kobs)
was determined and evaluated at different Fe3+ and H2O2 concentrations to find the best values for maximum efficiency.
In all the experiments the mineralization of an aqueous phenol solution was described by assuming a pseudo-first-order
reaction. The intrinsic kinetic constants not dependent on the lighting conditions were also estimated for scale-up.
2005 Elsevier Ltd. All rights reserved.
