Abstract :
A pesticide (Vydine) considered priority substances by the Jordanian environment ministry and dissolved in water at 25 mg L 1 (or at
maximum water solubility) has been degraded at solar pilot plant scale using direct solar UV-light, solar UV combined with H2O2 or
Fe(II) and solar photo-Fenton. Two different solar irradiation conditions (med day irradiation under clear sky and late hour irradiation
under clear sky) have been tested and discussed, using mainly pesticide concentration, TOC mineralization, COD removal and BOD for
comparison of treatment effectiveness. A cute toxicity assays were also employed for evaluating the photocatalytic treatments, and comparison
between these results. Direct solar UV photolysis is less efficient in term of pesticide degradation than other AOP’s. In contrast,
solar photo-Fenton reaction produced higher pesticide degradation in a shorter time (40 min was sufficient for 88% pesticide removal
with 20 mgL 1 H2O2 and 20 mg L 1 Fe (II)). In these conditions, the BOD5 was increased from zero for pure pesticide solution to
54 mg O2/L and acute toxicity was decreased from 19 to 6 toxicity unit.
2007 Elsevier Ltd. All rights reserved.
