Abstract :
Thin anatase TiO2 nanoleaves (NLs) with high surface area ( 93 m2/g) are synthesized by hydrothermal route and dye-sensitized
solar cells (DSSC) made using such NLs are compared with those made with hydro-thermally synthesized TiO2 nanoparticles and the
Degussa P25 powder. The NLs-based DSSCs show increment of 16% and 24% in the total conversion efficiency over the cells made with
NPs and P25 respectively. Interestingly, the highest increment in the conversion efficiency ( 35%) is achieved for cells made using a 50:50
(wt/wt) mixture of NLs and NPs. In this case the dye loading is found to be >50% higher than the case of NP films. Moreover the DC
resistance of diffusion of I 3 in electrolyte (as revealed by the electrochemical impedance spectroscopy) is substantially lower than the NP
film case, other cell parameters being nominally comparable.
2011 Elsevier Ltd. All rights reserved.
