Abstract :
Fibrous dye-sensitized solar cells (DSSCs) were fabricated using porous polyimide films prepared by the phase inversion technique
and their photovoltaic characteristics were investigated. A titanium wire was used as the photoelectrode substrate and a platinum wire
as the counter electrode. The platinum wire was coated with a porous polyimide film to prevent direct contact between the two electrodes
while facilitating electrolyte penetration through the pores. The pore size and pore size distribution of the porous polyimide films were
controlled by varying the immersion time in nonsolvent. With increased immersion time, the pore size distribution gradually broadened
as the pore size increased, enhancing electrolyte penetration. Increased electron transport owing to the enhanced electrolyte penetration
resulted in enhanced photovoltaic performances of the fibrous DSSC. The fibrous DSSC with 60 min immersion time had a short-circuit
current density (Jsc) of 0.0372 mA/cm2, an open-circuit voltage (Voc) of 0.182 V, and a fill factor (FF) of 0.33.
2012 Elsevier Ltd. All rights reserved.
