• Title of article

    Statistical mechanics of dipolar fluids: dielectric constant and sample shape

  • Author/Authors

    A. Alastuey، نويسنده , , V. Ballenegger، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2000
  • Pages
    19
  • From page
    268
  • To page
    286
  • Abstract
    We give a new proof that the constitutive relation of macroscopic electrostatics holds in a dipolar fluid with a sample shape independent dielectric constant. Our approach is based on a BGY-like hierarchy equation which allows us to calculate the canonical one-body density function up to linear order in the electric field, in the thermodynamic limit. The dielectric constant comes out as an integral over a 3-point correlation function of the infinite unperturbed (unpolarized) system, from which one can recover the well-known formula for in terms of the 2-point direct correlation function.
  • Journal title
    Physica A Statistical Mechanics and its Applications
  • Serial Year
    2000
  • Journal title
    Physica A Statistical Mechanics and its Applications
  • Record number

    866461