Title of article
Stereoselectivity in deoxygenation of 5-hydroxy-5-phosphinyl-hexofuranoses (α-hydroxyphosphonates) Original Research Article
Author/Authors
Tadashi Hanaya، نويسنده , , Ken-ichi Sugiyama، نويسنده , , Heizan Kawamoto، نويسنده , , Hiroshi Yamamoto، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2003
Pages
10
From page
1641
To page
1650
Abstract
The addition of dimethyl phosphonate to six different hexofuranos-5-uloses in the presence of DBU, followed by esterification with methoxalyl chloride and then radical reduction, afforded 5-deoxy-5-dimethoxyphosphinyl-d- and l-hexofuranoses. The stereoselectivity of the deoxygenation and possible transition-state models are discussed.
Keywords
Phospho sugar , ?-Hydroxyphosphonate , Deoxygenation
Journal title
Carbohydrate Research
Serial Year
2003
Journal title
Carbohydrate Research
Record number
963804
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