Title of article
Photoinduced electron-transfer α-deoxygenation of aldonolactones. Efficient synthesis of 2-deoxy-d-arabino-hexono-1,4-lactone Original Research Article
Author/Authors
Andrea Bordoni، نويسنده , , Rosa M. de Lederkremer، نويسنده , , Carla Marino، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2006
Pages
8
From page
1788
To page
1795
Abstract
A photoinduced electron-transfer (PET) reaction was used for the deoxygenation at C-2 of aldonolactones derivatized as 2-O-[3-(trifluoromethyl)benzoyl] or benzoyl esters. By irradiation of different d-galactono- and d-glucono-1,4-derivatives, with a 450 W lamp, using 9-methylcarbazole as photosensitizer, the corresponding 2-deoxy-d-lyxo- and 2-deoxy-d-arabino-hexono-1,4-lactones were efficiently obtained.
Keywords
Deoxy sugars , 2-Deoxy-d-arabino-1 , Aldonolactone photodeoxygenation , 4-lactone , 2-Deoxy-d-lyxono-1 , 4-lactone
Journal title
Carbohydrate Research
Serial Year
2006
Journal title
Carbohydrate Research
Record number
965801
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