Nitrogen in rainfall, cloud water, throughfall, stemflow, stream water and groundwater for the Plynlimon catchments of mid-Wales

An extensive study of acidic and acid sensitive moorland and forested catchments in mid-Wales is used to show the water quality functioning with respect to nitrate and ammonium. For this, long-term records of rainfall, cloud water, throughfall, stemflow and stream water (up to 18 years of weekly data) are combined with shorter duration information on stream water associated with small tributary sources and drainage ditches, ground water from a network of exploratory boreholes and paired control and felled catchments. The ratio of nitrate to ammonium is about one in rainfall, cloud water, throughfall and stemflow but the concentrations are much lower in rainfall ( 25 μM l−1) than in cloud water ( 300 μM l−1) while throughfall and stemflow are intermediate ( 80 μM l−1). Within the streams draining moorland and forested areas, nitrate concentrations are close to the mean value in rainfall while ammonium concentrations are often over an order of magnitude lower in the stream than in rainfall and are typically only about a fifth that of nitrate. With felling, stream water nitrate concentrations increase for podzolic soils but show a variable response for gley soils. For the streams draining forested podzols, the concentrations of nitrate can be up to an order of magnitude higher for the first few years after felling compared to than pre-fell values but in later years, concentrations decline to pre-fell and even lower levels. Felling for the podzolic soils barely leads to any changes in ammonium concentration. For the gley soils, felling results in an order of magnitude increase in nitrate and ammonium for a small drainage ditch, but the pulse barely reaches the main stream channel. Rather, within-catchment and within-stream processes not only take up the nitrate and ammonium fluxes generated, but in the case of nitrate, concentrations with- and post-felling are lower than pre-felling concentrations. Groundwater concentrations of nitrate for the moorland and forested catchments are slightly lower than for the streams while for ammonium the reverse is the case: ammonium concentrations in groundwater are about a tenth those of nitrate. With felling, groundwater nitrate concentrations show sporadic increases. For two boreholes, these increases occur during wet periods when groundwater levels are at their shallowest; for one other borehole, there is a gradual and sustained increase over several years. The results are explained in relation to the dominant hydrogeochemical processes operative.