Effect of clay content and wetting-and-drying on radiocaesium behaviour in a peat and a peaty podzol

The interaction of radiocaesium with peat under two moisture regimes was studied in laboratory experiments and by growing ryegrass in pot experiments to simulate changing field moisture conditions. A peat untreated and treated with 5% by weight of clay containing 46% illitic minerals, and a peaty podzol naturally containing 4.5% mineral matter on a dry weight basis were contaminated with 134Cs and incubated. The soils were exposed to 8 wetting-and-drying cycles or kept constantly wet during 40 days. Extraction of the peat with 1 M CH3COONH4 (pH 7) repeated after each wetting-and-drying cycle indicated increasing 134Cs fixation with time of incubation. The peat treated with clay showed a much higher 134Cs fixation than that without clay. The pot experiment with the incubated soils showed a 134Cs transfer to ryegrass of the same order for the peaty podzol as for the peat treated with clay. For the peat untreated with clay the 134Cs transfer to ryegrass was much greater. Wetting-and-drying the peat, with or without clay, increased the overall yield of grass and the concentration and uptake of 134Cs over 5 consecutive harvests. Kfertilisation increased the yield of plant material (except for the peat with added clay), decreased the concentration of 134Cs, but had no significant effect (p=0.05) on the resultant uptake of 134Cs. Mixing clay with the surface layer of organic soils appears to be an effective means of decreasing radiocaesium transfer to field crops in fallout situations.