Characterisation of acid mine drainage in a high rainfall mountain environment, New Zealand Original Research Article

The Stockton coal mine lies at 700–1100 m above sea level in a mountainous orographic precipitation zone on the West Coast of the South Island of New Zealand. Rainfall exceeds 6000 mm/year and arrives with frequent flood events that can deliver > 200 mm/day. Streams vary in discharges by up to two orders of magnitude over a time scale of hours. Pyritic waste rock at the mine interacts chemically with even the most intense rainfall, and almost all runoff is acidic to some degree. In the most intense rain event recorded in this study (> 10 mm/hour), dilution of acid mine drainage (AMD) occurred and pH rose from 3 to > 5 over several hours, with stream discharge at a monitoring point rising from < 0.5 to > 100 cumecs. However, most rain events of similar magnitude are less intense, longer duration, and only raise AMD pH to ~ 4 with similar high discharges. Results presented here for Stockton confirm that it is the intensity of rain events on the hourly scale, rather than the total amount of rainwater delivered to the site, that governs the amount and composition of AMD generated during flood events. Stream discharge loads of dissolved iron and aluminium range from ~ 20 to 1000 kg/hour. Dissolved sulfate and acidity loads are typically ~ 500 kg/hour but can exceed 20 tonnes/hour in rain events.